Most a/c contractors will know how old the HVAC system is, how well it has been maintained, and the quality of the work of the manufacturer of the equipment. They will check it for freon leaks and this is done with a freon leak detector, not freon guages. They will be able to tell what parts have been replaced. They will look to see if the breakers in the electrical panel matches the name plates over the current protective device. This Is A Must! With so much of the equipment being installed today, not to code and the high cost of replacement in this economy, don’t forget that most of the a/c contractor's work comes from home owners and not from realtors, unlike what home inspectors have to rely on. Note: If you choose to use a home inspector try to find out what they did before the became a home inspector.
Also, have the system cleaned and sanitized before you move in.
Hope this helps!